| Catalytic asymmetric addition of alkynylzinc reagents to ketones using polymer-supported chiral Schiff-base amino alcohols | |
| Department | 羰基合成与选择氧化国家重点实验室 |
| Chen C(陈超); Hong L(洪亮); Zhang BZ(张邦治); Wang R(王锐) | |
| 2008 | |
| Source Publication | Tetrahedron: Asymmetry
 |
| ISSN | 0957-4166 |
| Volume | 19Pages:191-196 |
| Abstract | Polymer-supported Schiff-base of optically active amino alcohols was used as chiral ligands in the enantioselective addition of alkynylzinc to simple ketones. At a 10 mol % ligand loading, chiral propargylic alcohols with moderate to good ee values (up to 89%) were produced. The polymeric catalyst could be recycled many times and used for further reactions. |
| Subject Area | 物理化学 |
| Funding Organization | the National Natural Science Foundation of China (Nos. 20772052;20472026;20525206);Chang Jiang Scholar Program of the Ministry of Education of China |
| Indexed By | SCI |
| Language | 英语 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/1931 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Wang R(王锐) |
| Recommended Citation GB/T 7714 | Chen C,Hong L,Zhang BZ,et al. Catalytic asymmetric addition of alkynylzinc reagents to ketones using polymer-supported chiral Schiff-base amino alcohols[J]. Tetrahedron: Asymmetry,2008,19:191-196. |
| APA | 陈超,洪亮,张邦治,&王锐.(2008).Catalytic asymmetric addition of alkynylzinc reagents to ketones using polymer-supported chiral Schiff-base amino alcohols.Tetrahedron: Asymmetry,19,191-196. |
| MLA | 陈超,et al."Catalytic asymmetric addition of alkynylzinc reagents to ketones using polymer-supported chiral Schiff-base amino alcohols".Tetrahedron: Asymmetry 19(2008):191-196. |
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| File Name/Size | DocType | Version | Access | License | ||
| 31_Tetrahedron Asymm（189KB） | 开放获取 | License | View Application Full Text | |||
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