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Facile Preparation of Monodisperse, Impurity-Free, and Antioxidation Copper Nanoparticles on a Large Scale for Application in Conductive Ink
Department固体润滑国家重点实验室
Zhang, Yu1,2,3; Zhu, Pengli1,4; Li, Gang1; Zhao, Tao1; Fu, Xianzhu1; Sun, Rong1; Zhou F(周峰)2; Wong, Ching-ping4,5
2014
Source PublicationACS Applied Materials and Interfaces
ISSN1944-8244
Volume6Issue:1Pages:560-567
AbstractMonodisperse copper nanoparticles with high purity and antioxidation properties are synthesized quickly (only 5 min) on a large scale (multigram amounts) by a modified polyol process using slightly soluble Cu(OH)2 as the precursor, l-ascorbic acid as the reductant, and PEG-2000 as the protectant. The resulting copper nanoparticles have a size distribution of 135 ± 30 nm and do not suffer significant oxidation even after being stored for 30 days under ambient conditions. The copper nanoparticles can be well-dispersed in an oil-based ink, which can be silk-screen printed onto flexible substrates and then converted into conductive patterns after heat treatment. An optimal electrical resistivity of 15.8 μΩ cm is achieved, which is only 10 times larger than that of bulk copper. The synthesized copper nanoparticles could be considered as a cheap and effective material for printed electronics.
KeywordCopper Nanoparticles Monodisperse Antioxidative Large Scale Flexible Conductors
Subject Area材料科学与物理化学
DOI10.1021/am404620y
Funding Organizationthe National Basic Research Program of China (973 Program) (2012CB933700-G);the National Natural Science Foundation of China (21101165);the Guangdong Innovative Research Team Program (no. 2011D052;KYPT20121228160843692);Shenzhen Electronic Packaging Materials Engineering Laboratory (2012-372);Shenzhen basic research plan (JC201005270372A;JC201005270366A;JSGG20120615161915279);the National S&T Major Project (2011ZX02709-001)
Indexed BySCI
If6.723
Language英语
Funding Project材料表面与界面行为研究组
compositor第二作者单位
Citation statistics
Cited Times:93[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/19266
Collection固体润滑国家重点实验室(LSL)
Corresponding AuthorZhu, Pengli; Sun, Rong
Affiliation1.Chinese Acad Sci, Shenzhen Inst Adv Technol, Shenzhen, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing, Peoples R China
4.Georgia Inst Technol, Sch Mat Sci & Engn, Atlanta, GA 30332 USA
5.Chinese Univ Hong Kong, Dept Elect Engn, Hong Kong, Hong Kong, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Yu,Zhu, Pengli,Li, Gang,et al. Facile Preparation of Monodisperse, Impurity-Free, and Antioxidation Copper Nanoparticles on a Large Scale for Application in Conductive Ink[J]. ACS Applied Materials and Interfaces,2014,6(1):560-567.
APA Zhang, Yu.,Zhu, Pengli.,Li, Gang.,Zhao, Tao.,Fu, Xianzhu.,...&Wong, Ching-ping.(2014).Facile Preparation of Monodisperse, Impurity-Free, and Antioxidation Copper Nanoparticles on a Large Scale for Application in Conductive Ink.ACS Applied Materials and Interfaces,6(1),560-567.
MLA Zhang, Yu,et al."Facile Preparation of Monodisperse, Impurity-Free, and Antioxidation Copper Nanoparticles on a Large Scale for Application in Conductive Ink".ACS Applied Materials and Interfaces 6.1(2014):560-567.
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