| Gold-Catalyzed 1,2-Acyloxy Migration/Intramolecular [3+2] 1,3-Dipolar Cycloaddtion Cascade Reaction: An Efficient Strategy for Syntheses of Medium-Sized-Ring Ethers and Amines | |
| Department | OSSO国家重点实验室 |
| Zhao, Changgui1; Xie, Xingang1; Duan, Shuangshuang1; Li, Huilin1; Fang, Ran1; She XG(厍学功)1,2 | |
| 2014 | |
| Source Publication | Angewandte Chemie International Edition
 |
| ISSN | 1433-7851 |
| Volume | 53Issue:40Pages:10789-10793 |
| Abstract | A highly efficient strategy for the formation of medium-sized-ring ethers and amines based on a gold-catalyzed cascade reaction, involving enynyl ester isomerization and intramolecular [3+2] cyclization, has been developed. Various multisubstituted medium-sized-ring unsaturated ethers and amines were obtained through this transformation. This method represents one of the relatively few transition metal catalyzed intramolecular cycloaddition reactions for medium-sized ring synthesis. |
| Keyword | Cycloaddition Gold Heterocycles Medium-ring Compounds Synthetic Methods |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1002/anie.201406486 |
| Funding Organization | the Fundamental Research Funds for MOST (2010CB833200);the NSFC (21125207;21372103;21102062;21203080);SRFDP (20130211110018) |
| Indexed By | SCI |
| If | 11.261 |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/19248 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Affiliation | 1.Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China |
| Recommended Citation GB/T 7714 | Zhao, Changgui,Xie, Xingang,Duan, Shuangshuang,et al. Gold-Catalyzed 1,2-Acyloxy Migration/Intramolecular [3+2] 1,3-Dipolar Cycloaddtion Cascade Reaction: An Efficient Strategy for Syntheses of Medium-Sized-Ring Ethers and Amines[J]. Angewandte Chemie International Edition,2014,53(40):10789-10793. |
| APA | Zhao, Changgui,Xie, Xingang,Duan, Shuangshuang,Li, Huilin,Fang, Ran,&She XG.(2014).Gold-Catalyzed 1,2-Acyloxy Migration/Intramolecular [3+2] 1,3-Dipolar Cycloaddtion Cascade Reaction: An Efficient Strategy for Syntheses of Medium-Sized-Ring Ethers and Amines.Angewandte Chemie International Edition,53(40),10789-10793. |
| MLA | Zhao, Changgui,et al."Gold-Catalyzed 1,2-Acyloxy Migration/Intramolecular [3+2] 1,3-Dipolar Cycloaddtion Cascade Reaction: An Efficient Strategy for Syntheses of Medium-Sized-Ring Ethers and Amines".Angewandte Chemie International Edition 53.40(2014):10789-10793. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Zhao_et_al-2014-Ange（429KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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