| ANION-BINDING AND SENSING PROPERTIES OF NOVEL RECEPTORS BASED ON N-(INDOL-3-YLGLYOXYLYL)BENZYLAMINE | |
| Department | 中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 |
Wei, Wei1; Lv, Yong Jun1; Shao SJ(邵士俊)2,3 ; Guo Y(郭勇)2,3
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| 2015 | |
| Source Publication | Química Nova
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| ISSN | 0100-4042 |
| Volume | 38Issue:10Pages:1293-1296 |
| Abstract | Indole-based receptors such as biindole, carbazole, and indolocarbazole are regarded as some of the most favorable anion receptors in molecular recognition. This is because indole groups possess N-H groups as hydrogen-bonding donors. The introduction of amide groups in the indole framework can induce strong binding properties and good water solubility. In this study, we designed and synthesized a series of N-(indol-3-ylglyoxylyl)benzylamine derivatives as novel and simple anion receptors. The receptors derived by aryl and aliphatic amines can selectively recognize F- based on a color change from colorless-to-yellow in DMSO. The receptors derived by hydrazine hydrate can recognize F-, AcO-, and H2PO4- by similar color changes in DMSO and can even enable the selective recognition of F- in a DMSO-H2O binary solution by the naked eye. Spectrographic data indicate that complexes are formed between receptors and anions through multiple hydrogen-bonding interactions in dual solutions. |
| Keyword | Anion Recognition Indoly Benzylamine Hydrogen Bonds Spectroscopy |
| Subject Area | 分析化学与药物化学 |
| DOI | 10.5935/0100-4042.20150157 |
| Funding Organization | the talent introduction project of Sichuan University of Science and Engineering (No. 211RC14) |
| Indexed By | SCI |
| If | 0.617 |
| Language | 英语 |
| Funding Project | 药物分子识别研究组;药物分离材料研究组 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/19220 |
| Collection | 中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 |
| Corresponding Author | Wei, Wei |
| Affiliation | 1.Sichuan Univ Sci & Engn, Mat & Chem Engn Coll, Zigong 643000, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, Key Lab Chem Northwestern Plant Resources, Lanzhou 730000, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, Key Lab Nat Med Gansu Prov, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Wei, Wei,Lv, Yong Jun,Shao SJ,et al. ANION-BINDING AND SENSING PROPERTIES OF NOVEL RECEPTORS BASED ON N-(INDOL-3-YLGLYOXYLYL)BENZYLAMINE[J]. Química Nova,2015,38(10):1293-1296. |
| APA | Wei, Wei,Lv, Yong Jun,Shao SJ,&Guo Y.(2015).ANION-BINDING AND SENSING PROPERTIES OF NOVEL RECEPTORS BASED ON N-(INDOL-3-YLGLYOXYLYL)BENZYLAMINE.Química Nova,38(10),1293-1296. |
| MLA | Wei, Wei,et al."ANION-BINDING AND SENSING PROPERTIES OF NOVEL RECEPTORS BASED ON N-(INDOL-3-YLGLYOXYLYL)BENZYLAMINE".Química Nova 38.10(2015):1293-1296. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| v38n10a07.pdf（960KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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