| Aromatic-Amide-Derived Nonbiaryl Atropisomer as Highly Efficient Ligand for Asymmetric Silver-Catalyzed [3+2] Cycloaddition | |
| Department | OSSO国家重点实验室 |
Bai XF(柏惺峰)1,2,3; Xu, Zheng3; Xia CG(夏春谷)1,2 ; Zheng ZJ(郑战江)3; Xu LW(徐利文)1,2,3; Xia CG(夏春谷); Xu LW(徐利文)
| |
| 2015 | |
| Source Publication | ACS Catalysis
 |
| ISSN | 2155-5435 |
| Volume | 5Issue:10Pages:6016-6020 |
| Abstract | In this work, we have successfully determined that the aromatic amide-derived nonbiaryl atropisomer/silver complex (silver-Xing-Phos) is an effective catalyst system for the solvent-dependent exo-selective cycloaddition of glycine aldimino esters with chalcones or less-reactive methyl cinnamates to give the corresponding chalcone- or cinnamate-derived pyrrolidines with multiple stereogenic centers in good yields and high diastereoselectivities as well as excellent enantioselectivities. Remarkably, it is the first example of highly enantioselective silver-catalyzed [3 + 2] cycloaddition of methyl cinnamates with glycine aldimino esters. |
| Keyword | Asymmetric Catalysis Pyrrolidines Silver Homogeneous Catalysis Atropisomers Cycloaddition |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1021/acscatal.5b01685 |
| Funding Organization | the National Natural Science Founder of China (No. 21173064;21133011;21472031);Zhejiang Provincial Natural Science Foundation of China (LR14B030001) |
| Indexed By | SCI |
| If | 9.307 |
| Language | 英语 |
| Funding Project | 均相催化课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/19155 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Xia CG(夏春谷); Xu LW(徐利文) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Lanzhou 730000, Peoples R China 3.Hangzhou Normal Univ, Minist Educ, Key Lab Organosilicon Chem & Mat Technol, Hangzhou 311121, Zhejiang, Peoples R China |
| Recommended Citation GB/T 7714 | Bai XF,Xu, Zheng,Xia CG,et al. Aromatic-Amide-Derived Nonbiaryl Atropisomer as Highly Efficient Ligand for Asymmetric Silver-Catalyzed [3+2] Cycloaddition[J]. ACS Catalysis,2015,5(10):6016-6020. |
| APA | Bai XF.,Xu, Zheng.,Xia CG.,Zheng ZJ.,Xu LW.,...&徐利文.(2015).Aromatic-Amide-Derived Nonbiaryl Atropisomer as Highly Efficient Ligand for Asymmetric Silver-Catalyzed [3+2] Cycloaddition.ACS Catalysis,5(10),6016-6020. |
| MLA | Bai XF,et al."Aromatic-Amide-Derived Nonbiaryl Atropisomer as Highly Efficient Ligand for Asymmetric Silver-Catalyzed [3+2] Cycloaddition".ACS Catalysis 5.10(2015):6016-6020. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| acscatal.5b01685.pdf（1060KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment