Hydrothermal Synthesis and Upconversion Properties of alpha-NaYF4:Yb3+, Er3+ Nanocrystals Using Citric Acid as Chelating Ligand and NaNO3 as Mineralizer | |
Department | 固体润滑国家重点实验室 |
Wang, Chuanying1; Cheng XH(程先华)1,2; Cheng XH(程先华) | |
2015 | |
Source Publication | Journal of Nanoscience and Nanotechnology |
ISSN | 1533-4880 |
Volume | 15Issue:12Pages:9656-9664 |
Abstract | Yb3+ and Er3+ ions co-doped α-NaYF4:Yb3+, Er3+ nanocrystals were successfully synthesized via a facile hydrothermal method using citric acid (CA) as chelating ligand and NaNO3 as mineralizer. The influences of the CA/RE (RE= Y+Yb+Er) molar ratio, reaction time, reaction temperature and the NaNO3/RE molar ratio on the crystal phases and shapes of as-prepared products have been well investigated. The possible formation mechanism has been discussed in detail and an aggregation growth theory has been proposed. X-ray diffraction (XRD), transmission electron microscopy (TEM), selected area electron diffraction (SAED), scanning electron microscopy (SEM), and photoluminescence (PL) spectra were used to characterize the products. Under 980 nm excitation, the emission intensities of the as-prepared nanocrystals were much stronger than that of the nanocrystals modified by ethylenediaminetetraacetic acid (EDTA). Additionally, the as-prepared products maintained spherical shape and high degree of monodispersion, which is expected to be suggestive for the preparation of other complex rare earth fluoride compounds. |
Keyword | Cubic Nayf4 Citric Acid Nanocrystals Photoluminescence |
Subject Area | 材料科学与物理化学 |
DOI | 10.1166/jnn.2015.10330 |
Funding Organization | the National Science Foundation of China (Grant No. 51175330) |
Indexed By | SCI |
If | 1.338 |
Language | 英语 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/19117 |
Collection | 固体润滑国家重点实验室(LSL) |
Corresponding Author | Cheng XH(程先华) |
Affiliation | 1.Shanghai Jiao Tong Univ, Sch Mech Engn, Shanghai 200240, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China |
Recommended Citation GB/T 7714 | Wang, Chuanying,Cheng XH,Cheng XH. Hydrothermal Synthesis and Upconversion Properties of alpha-NaYF4:Yb3+, Er3+ Nanocrystals Using Citric Acid as Chelating Ligand and NaNO3 as Mineralizer[J]. Journal of Nanoscience and Nanotechnology,2015,15(12):9656-9664. |
APA | Wang, Chuanying,Cheng XH,&程先华.(2015).Hydrothermal Synthesis and Upconversion Properties of alpha-NaYF4:Yb3+, Er3+ Nanocrystals Using Citric Acid as Chelating Ligand and NaNO3 as Mineralizer.Journal of Nanoscience and Nanotechnology,15(12),9656-9664. |
MLA | Wang, Chuanying,et al."Hydrothermal Synthesis and Upconversion Properties of alpha-NaYF4:Yb3+, Er3+ Nanocrystals Using Citric Acid as Chelating Ligand and NaNO3 as Mineralizer".Journal of Nanoscience and Nanotechnology 15.12(2015):9656-9664. |
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