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Hydrothermal Synthesis and Upconversion Properties of alpha-NaYF4:Yb3+, Er3+ Nanocrystals Using Citric Acid as Chelating Ligand and NaNO3 as Mineralizer
Department固体润滑国家重点实验室
Wang, Chuanying1; Cheng XH(程先华)1,2; Cheng XH(程先华)
2015
Source PublicationJournal of Nanoscience and Nanotechnology
ISSN1533-4880
Volume15Issue:12Pages:9656-9664
AbstractYb3+ and Er3+ ions co-doped α-NaYF4:Yb3+, Er3+ nanocrystals were successfully synthesized via a facile hydrothermal method using citric acid (CA) as chelating ligand and NaNO3 as mineralizer. The influences of the CA/RE (RE= Y+Yb+Er) molar ratio, reaction time, reaction temperature and the NaNO3/RE molar ratio on the crystal phases and shapes of as-prepared products have been well investigated. The possible formation mechanism has been discussed in detail and an aggregation growth theory has been proposed. X-ray diffraction (XRD), transmission electron microscopy (TEM), selected area electron diffraction (SAED), scanning electron microscopy (SEM), and photoluminescence (PL) spectra were used to characterize the products. Under 980 nm excitation, the emission intensities of the as-prepared nanocrystals were much stronger than that of the nanocrystals modified by ethylenediaminetetraacetic acid (EDTA). Additionally, the as-prepared products maintained spherical shape and high degree of monodispersion, which is expected to be suggestive for the preparation of other complex rare earth fluoride compounds.
KeywordCubic Nayf4 Citric Acid Nanocrystals Photoluminescence
Subject Area材料科学与物理化学
DOI10.1166/jnn.2015.10330
Funding Organizationthe National Science Foundation of China (Grant No. 51175330)
Indexed BySCI
If1.338
Language英语
compositor第二作者单位
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/19117
Collection固体润滑国家重点实验室(LSL)
Corresponding AuthorCheng XH(程先华)
Affiliation1.Shanghai Jiao Tong Univ, Sch Mech Engn, Shanghai 200240, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
Recommended Citation
GB/T 7714
Wang, Chuanying,Cheng XH,Cheng XH. Hydrothermal Synthesis and Upconversion Properties of alpha-NaYF4:Yb3+, Er3+ Nanocrystals Using Citric Acid as Chelating Ligand and NaNO3 as Mineralizer[J]. Journal of Nanoscience and Nanotechnology,2015,15(12):9656-9664.
APA Wang, Chuanying,Cheng XH,&程先华.(2015).Hydrothermal Synthesis and Upconversion Properties of alpha-NaYF4:Yb3+, Er3+ Nanocrystals Using Citric Acid as Chelating Ligand and NaNO3 as Mineralizer.Journal of Nanoscience and Nanotechnology,15(12),9656-9664.
MLA Wang, Chuanying,et al."Hydrothermal Synthesis and Upconversion Properties of alpha-NaYF4:Yb3+, Er3+ Nanocrystals Using Citric Acid as Chelating Ligand and NaNO3 as Mineralizer".Journal of Nanoscience and Nanotechnology 15.12(2015):9656-9664.
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