Recent Advances in Transition-Metal-Catalyzed Silylations of Arenes with Hydrosilanes: C-X Bond Cleavage or C-H Bond Activation Synchronized with Si-H Bond Activation | |
Department | OSSO国家重点实验室 |
Xu, Zheng1; Huang, Wei-Sheng1; Zhang, Jin1; Xu LW(徐利文)1,2; Xu LW(徐利文) | |
2015 | |
Source Publication | SYNTHESIS-STUTTGART |
ISSN | 0039-7881 |
Volume | 47Issue:23Pages:3645-3668 |
Abstract | Arylsilanes are valuable organosilicon compounds and attract significant research interest due to their promising applications in organic synthesis. The development of aromatic C–Si cross-coupling reactions represents a major challenge in both organosilicon chemistry and organic synthesis. A number of investigations are focused on developing transition-metal-catalyzed Si–C coupling reactions due to the associated high atom economy and superior functional group compatibility. This review describes recent advances in transition-metal-catalyzed selective silylations of aryl C–H and C–X (X = halide) bonds with hydrosilanes. |
Keyword | Arylsilanes Transition Metal Silylation Homogeneous Catalysis Cross-coupling |
Subject Area | 物理化学与绿色催化 ; 物理化学与绿色催化 |
DOI | 10.1055/s-0035-1560646 |
Funding Organization | the National Natural Science Foundation of China (No. 21173064;21472031);Zhejiang Provincial Natural Science Foundation of China (LR14B030001);the Program for Excellent Young Teachers in Hangzhou Normal University (HNUEYT, JTAS 2011-01-014;JTAS 2011-01-017) |
Indexed By | SCI |
If | 2.652 |
Language | 英语 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/19109 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Xu, Zheng; Xu LW(徐利文) |
Affiliation | 1.Hangzhou Normal Univ, Key Lab Organosilicon Chem & Mat Technol, Minist Educ, Hangzhou, Zhejiang, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
Recommended Citation GB/T 7714 | Xu, Zheng,Huang, Wei-Sheng,Zhang, Jin,et al. Recent Advances in Transition-Metal-Catalyzed Silylations of Arenes with Hydrosilanes: C-X Bond Cleavage or C-H Bond Activation Synchronized with Si-H Bond Activation[J]. SYNTHESIS-STUTTGART,2015,47(23):3645-3668. |
APA | Xu, Zheng,Huang, Wei-Sheng,Zhang, Jin,Xu LW,&徐利文.(2015).Recent Advances in Transition-Metal-Catalyzed Silylations of Arenes with Hydrosilanes: C-X Bond Cleavage or C-H Bond Activation Synchronized with Si-H Bond Activation.SYNTHESIS-STUTTGART,47(23),3645-3668. |
MLA | Xu, Zheng,et al."Recent Advances in Transition-Metal-Catalyzed Silylations of Arenes with Hydrosilanes: C-X Bond Cleavage or C-H Bond Activation Synchronized with Si-H Bond Activation".SYNTHESIS-STUTTGART 47.23(2015):3645-3668. |
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