Surface structural changes, surface energy and antiwear properties of polytetrafluoroethylene induced by proton irradiation
Department先进润滑与防护材料研究发展中心
Lv M(吕美)1,2; Zheng F(郑菲)1,2; Wang QH(王齐华)1; Wang TM(王廷梅)1; Liang YM(梁永民)3; Wang QH(王齐华)
The second department固体润滑国家重点实验室
2015
Source PublicationMaterials and Design
ISSN0261-3069
Volume85Pages:162-168
AbstractIn this work, the polytetrafluoroethylene (PTFE) surface was modified with 25 keV proton beam irradiation in vacuum condition. Multiple characterization techniques including X-ray photoelectron spectroscopy, Raman spectroscopy and infrared spectroscopy were employed for research on microstructure changes in the PTFE surface. The changes in the surface energy and antiwear properties of PTFE were evaluated using contact angle analysis and a ball-on-disk tribometer, respectively. Experimental results showed that the surface energy of PTFE obviously increased from 13.17 mJ/m2 to 33.73 mJ/m2 and the wear rate decreased from 8.9 × 10− 3 mm3/Nm to 5.8 × 10− 4 mm3/Nm after proton irradiation for 15 min. Moreover, TRIM simulation indicated that the H+ ions cannot penetrate through the PTFE block and only stop at a depth of about 730 nm from the material surface. Proton irradiation has been proved to be a simple, rapid and effective measure for the surface modification of PTFE with distinctly improved surface energy and antiwear properties, and the possible reaction mechanism taking place in PTFE was also discussed in this paper.
KeywordPolytetrafluoroethylene Surface Modification Proton Irradiation Surface Energy Antiwear Properties
Subject Area材料科学与物理化学
DOI10.1016/j.matdes.2015.06.155
Funding Organizationthe National Basic Research Program of China (973 Program, Grant No. 2015CB057502);the National Defense Innovation Fund of Chinese Academy of Sciences (CXJJ-14-M43)
Indexed BySCI
If3.997
Language英语
Funding Project聚合物自润滑复合材料组
compositor第一作者单位
Citation statistics
Cited Times:24[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/19072
Collection中国科学院材料磨损与防护重点实验室/先进润滑与防护材料研究发展中心
固体润滑国家重点实验室(LSL)
Corresponding AuthorWang QH(王齐华)
Affiliation1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China
3.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China
Recommended Citation
GB/T 7714
Lv M,Zheng F,Wang QH,et al. Surface structural changes, surface energy and antiwear properties of polytetrafluoroethylene induced by proton irradiation[J]. Materials and Design,2015,85:162-168.
APA Lv M,Zheng F,Wang QH,Wang TM,Liang YM,&王齐华.(2015).Surface structural changes, surface energy and antiwear properties of polytetrafluoroethylene induced by proton irradiation.Materials and Design,85,162-168.
MLA Lv M,et al."Surface structural changes, surface energy and antiwear properties of polytetrafluoroethylene induced by proton irradiation".Materials and Design 85(2015):162-168.
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