| Facile Synthesis of Trisubstituted Carbazoles by Acid-Catalyzed Ring-Opening Annulation of 2-Amidodihydrofurans with Indoles | |
| Department | OSSO国家重点实验室 |
Zhao JJ(赵静静)1,2; Li P(李盼)1; Xia CG(夏春谷)1 ; Li FW(李福伟)1; Li FW(李福伟)
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| 2015 | |
| Source Publication | Chemistry - A European Journal
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| ISSN | 0947-6539 |
| Volume | 21Issue:46Pages:16383-16386 |
| Abstract | A mild and convenient synthesis of carbazoles by TfOTMS (trimethylsilyl trifluoromethanesulfonate)-catalyzed ring-opening annulation of 2-amidodihydrofurans is presented with a high degree of chemoselectivity and regioselectivity. This procedure was also scaled up to a gram-scale synthesis. The reaction could involve an iminonium intermediate through a series of CO, CN bond cleavages, CC bond formations, and a 1,2-migration process. |
| Keyword | Acid-catalysis Carbazoles Chemoselectivity Regioselectivity Ring-opening Annulation |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1002/chem.201503260 |
| Funding Organization | the Chinese Academy of Science;the National Natural Science Foundation of China (21133011;21373246;21522309) |
| Indexed By | SCI |
| If | 5.771 |
| Language | 英语 |
| Funding Project | 均相催化课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/18893 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Li FW(李福伟) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth Oxidat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| Recommended Citation GB/T 7714 | Zhao JJ,Li P,Xia CG,et al. Facile Synthesis of Trisubstituted Carbazoles by Acid-Catalyzed Ring-Opening Annulation of 2-Amidodihydrofurans with Indoles[J]. Chemistry - A European Journal,2015,21(46):16383-16386. |
| APA | Zhao JJ,Li P,Xia CG,Li FW,&李福伟.(2015).Facile Synthesis of Trisubstituted Carbazoles by Acid-Catalyzed Ring-Opening Annulation of 2-Amidodihydrofurans with Indoles.Chemistry - A European Journal,21(46),16383-16386. |
| MLA | Zhao JJ,et al."Facile Synthesis of Trisubstituted Carbazoles by Acid-Catalyzed Ring-Opening Annulation of 2-Amidodihydrofurans with Indoles".Chemistry - A European Journal 21.46(2015):16383-16386. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Zhao_et_al-2015-Chem（1089KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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