Electrodeposition of zinc-cobalt alloys from choline chloride-urea ionic liquid | |
Department | 固体润滑国家重点实验室 |
Chu QW(初青伟)1,2; Liang J(梁军)1; Hao JC(郝京诚)1; Liang J(梁军); Hao JC(郝京诚) | |
2014 | |
Source Publication | Electrochimica Acta |
ISSN | 0013-4686 |
Volume | 115Pages:499-503 |
Abstract | The electrodeposition behavior of zinc-cobalt (Zn-Co) alloy was investigated in choline chloride/urea (1:2 molar ratio) deep eutectic solvent containing 0.11 M ZnCl2 and 0.01 M CoCl2. Cyclic voltammetry revealed that Co reduced preferably with respect to Zn and anomalous codeposition of Zn-Co did not occur in this solvent. Chronoamperometric investigations combined with field emission scanning electron microscopy (FE-SEM) indicated that the electrodeposition of Zn-Co alloys followed the mechanism of instantaneous nucleation. Energy dispersive spectroscopy (EDS), grazing incidence X-ray diffraction (GI-XRD) and SEM results showed that the deposition potential influenced the compositions, phase structure and surface morphology of the Zn-Co alloys. |
Keyword | Electrodeposition Ionic Liquid Zn-co Alloy Codeposition Mechanism |
Subject Area | 材料科学与物理化学 |
DOI | 10.1016/j.electacta.2013.10.204 |
Funding Organization | National Natural Science Foundation of China (Grant No. 51305432);the “Hundred Talents Program” of Chinese Academy of Sciences (J. Liang) |
Indexed By | SCI |
If | 4.504 |
Language | 英语 |
Funding Project | 空间润滑材料组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/18780 |
Collection | 固体润滑国家重点实验室(LSL) |
Corresponding Author | Liang J(梁军); Hao JC(郝京诚) |
Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China |
Recommended Citation GB/T 7714 | Chu QW,Liang J,Hao JC,et al. Electrodeposition of zinc-cobalt alloys from choline chloride-urea ionic liquid[J]. Electrochimica Acta,2014,115:499-503. |
APA | Chu QW,Liang J,Hao JC,梁军,&郝京诚.(2014).Electrodeposition of zinc-cobalt alloys from choline chloride-urea ionic liquid.Electrochimica Acta,115,499-503. |
MLA | Chu QW,et al."Electrodeposition of zinc-cobalt alloys from choline chloride-urea ionic liquid".Electrochimica Acta 115(2014):499-503. |
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2014499-503.pdf(1956KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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