| One-pot synthesis of ordered mesoporous transition metal-zirconium oxophosphate composites with excellent textural and catalytic properties | |
| Department | OSSO国家重点实验室 |
Miao ZC(苗智超)1,2 ; Zhao HH(赵华华)1; Yang J(杨建)1; Zhao J(赵军)1; Song HL(宋焕玲)1,3; Chou LJ(丑凌军)1,3; Chou LJ(丑凌军)
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| 2015 | |
| Source Publication | New Journal of Chemistry
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| ISSN | 1144-0546 |
| Volume | 39Issue:2Pages:1322-1329 |
| Abstract | A series of ordered mesoporous transition metal-zirconium oxophosphate composites (M-X-ZrPO, X = Cr, Mn, Fe, Co, Ni, Cu, Zn) were designed and synthesized via a facile and general one-pot evaporation-induced self-assembly (EISA) method. N2-physisorption and TEM characterization showed that all the final materials possessed ordered mesoporous structure accompanied by large specific surface area (170-220 m2 g-1), big pore volume (0.2-0.4 cm3 g-1) and uniform pore size (5.6-7.8 nm). Moreover, the introduced transition metals homogeneously dispersed in the mesoporous skeleton and effectively improved the mesostructure. The catalytic performance of M-X-ZrPO was evaluated in the liquid phase oxidation of ethylbenzene. The introduced transition metals obviously enhanced the catalytic performance of M-ZrPO. M-Mn-ZrPO showed excellent catalytic activity with 91.6% conversion of ethylbenzene and 87.0% selectivity of acetophenone. After five cycles, there was no notable decrease in catalytic activity. Therefore, it was a promising catalyst for the oxidation of ethylbenzene. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1039/c4nj01227e |
| Funding Organization | the "Strategic Priority Research Program" of the Chinese Academy of Sciences, Grant no. XDA09030101;the National Natural Science Foundation of China (No. 21133011;21373244) |
| Indexed By | SCI |
| If | 3.277 |
| Language | 英语 |
| Funding Project | 多相选择氧化课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/18684 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Chou LJ(丑凌军) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Suzhou Inst Nanotech & Nanobion, Suzhou 215123, Peoples R China |
| Recommended Citation GB/T 7714 | Miao ZC,Zhao HH,Yang J,et al. One-pot synthesis of ordered mesoporous transition metal-zirconium oxophosphate composites with excellent textural and catalytic properties[J]. New Journal of Chemistry,2015,39(2):1322-1329. |
| APA | Miao ZC.,Zhao HH.,Yang J.,Zhao J.,Song HL.,...&丑凌军.(2015).One-pot synthesis of ordered mesoporous transition metal-zirconium oxophosphate composites with excellent textural and catalytic properties.New Journal of Chemistry,39(2),1322-1329. |
| MLA | Miao ZC,et al."One-pot synthesis of ordered mesoporous transition metal-zirconium oxophosphate composites with excellent textural and catalytic properties".New Journal of Chemistry 39.2(2015):1322-1329. |
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| Miao-2015-One-pot sy（3656KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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