LICP OpenIR  > 羰基合成与选择氧化国家重点实验室(OSSO)
DDQ/tert-Butyl nitrite-catalyzed aerobic oxidation of diarylmethane sp(3) C-H bonds
DepartmentOSSO国家重点实验室
Ma, Jiaqi1; Hu, Zhiming1; Li, Meichao1; Zhao, Weijuan2; Hu XQ(胡信全)1,3; Mo WM(莫卫民)1; Hu BX(胡宝祥)1; Sun N(孙楠)1; Shen ZL(沈振陆)1; Shen ZL(沈振陆)
2015
Source PublicationTetrahedron
ISSN0040-4020
Volume71Issue:38Pages:6733-6739
Abstract

An efficient 2,3-dichloro-5,6-dicyano-1,4-benzoquinone/tert-butyl nitrite-catalyzed aerobic oxidation of diarylmethane sp(3) C-H bonds in the presence of acetic acid has been developed. Under the optimal reaction conditions, a number of diarylmethanes can be directly converted to their corresponding diarylketones in good to excellent yields. In addition, a plausible reaction mechanism has been investigated.

KeywordOxidation Diarylmethanes Diaryketones Oxygen
Subject Area物理化学与绿色催化
DOI10.1016/j.canlet.2015.07.042
Funding Organizationthe Natural Science Foundation of China (NSFC 21376224;21206147);Opening Foundation of Zhejiang Key Course of Chemical Engineering and Technology, Zhejiang University of Technology (20130211)
Indexed BySCI
If2.645
Language英语
compositor第三作者单位
Citation statistics
Cited Times:47[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/18569
Collection羰基合成与选择氧化国家重点实验室(OSSO)
Corresponding AuthorShen ZL(沈振陆)
Affiliation1.Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310014, Zhejiang, Peoples R China
2.Zhejiang Res Inst Chem Ind Ltd, Hangzhou 310023, Zhejiang, Peoples R China
3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
Recommended Citation
GB/T 7714
Ma, Jiaqi,Hu, Zhiming,Li, Meichao,et al. DDQ/tert-Butyl nitrite-catalyzed aerobic oxidation of diarylmethane sp(3) C-H bonds[J]. Tetrahedron,2015,71(38):6733-6739.
APA Ma, Jiaqi.,Hu, Zhiming.,Li, Meichao.,Zhao, Weijuan.,Hu XQ.,...&沈振陆.(2015).DDQ/tert-Butyl nitrite-catalyzed aerobic oxidation of diarylmethane sp(3) C-H bonds.Tetrahedron,71(38),6733-6739.
MLA Ma, Jiaqi,et al."DDQ/tert-Butyl nitrite-catalyzed aerobic oxidation of diarylmethane sp(3) C-H bonds".Tetrahedron 71.38(2015):6733-6739.
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