LICP OpenIR  > 羰基合成与选择氧化国家重点实验室(OSSO)
Construction of an all-substituted pyrrolidine derivative with multiple stereogenic centers and Betti-base-derived gamma-amino alcohols by [1,2]-Wittig rearrangement
DepartmentOSSO国家重点实验室
Wang, Cai-Yun1; Dong, Cheng1; Zheng ZJ(郑战江)1; Xu, Zheng1; Yang KF(杨科芳)1; Xu LW(徐利文)1,2; Zheng ZJ(郑战江); Xu LW(徐利文)
2015
Source PublicationRSC Advances
ISSN2046-2069
Volume5Issue:69Pages:55819-55824
Abstract

A new class of substituted γ-amino alcohols and downstream pyrrolidine derivatives have been synthesized successfully from simple 1-phenyl-ethylamine, in which a representative all-substituted pyrrolidine derivative with multiple stereogenic centers was obtained by highly diastereoselective [1,2]-Wittig rearrangement and intramolecular cyclization with perfect chirality transfer (up to >99.9% de) and good yields.

Subject Area物理化学与绿色催化
DOI10.1039/c5ra09145d
Funding Organizationthe National Natural Science Founder of China (No. 21173064;51303043;21472031);Zhejiang Provincial Natural Science Foundation of China (LR14B030001)
Indexed BySCI
If3.840
Language英语
compositor第二作者单位
Citation statistics
Cited Times:12[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/18517
Collection羰基合成与选择氧化国家重点实验室(OSSO)
Corresponding AuthorZheng ZJ(郑战江); Xu LW(徐利文)
Affiliation1.Hangzhou Normal Univ, Key Lab Organosilicon Chem & Mat Technol, Minist Educ MOE, Hangzhou 311121, Zhejiang, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
Recommended Citation
GB/T 7714
Wang, Cai-Yun,Dong, Cheng,Zheng ZJ,et al. Construction of an all-substituted pyrrolidine derivative with multiple stereogenic centers and Betti-base-derived gamma-amino alcohols by [1,2]-Wittig rearrangement[J]. RSC Advances,2015,5(69):55819-55824.
APA Wang, Cai-Yun.,Dong, Cheng.,Zheng ZJ.,Xu, Zheng.,Yang KF.,...&徐利文.(2015).Construction of an all-substituted pyrrolidine derivative with multiple stereogenic centers and Betti-base-derived gamma-amino alcohols by [1,2]-Wittig rearrangement.RSC Advances,5(69),55819-55824.
MLA Wang, Cai-Yun,et al."Construction of an all-substituted pyrrolidine derivative with multiple stereogenic centers and Betti-base-derived gamma-amino alcohols by [1,2]-Wittig rearrangement".RSC Advances 5.69(2015):55819-55824.
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