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A facile preparation and electrochemical properties of nickel based compound-graphene sheet composites for supercapacitors
Department固体润滑国家重点实验室
Zhang, Li-Bin1,3; Yang SR(杨生荣)1; Wang JQ(王金清)1; Xu Y(许晔)1; Kong, Xiang-Zheng2; Yang SR(杨生荣)
2015
Source PublicationChinese Chemical Letters
ISSN1001-8417
Volume26Issue:5Pages:522-528
AbstractComposites of a nickel based compound incorporated with graphene sheets (NiBC-GS) are prepared by a simple flocculation, using hydrazine hydrate as flocculant and reductant, from a homogeneous intermixture of nickel dichloride and graphene oxide dispersed in N,N-dimethylformamide. Morphology, microstructure and thermal stability of the obtained products were characterized by field-emission scanning electron microscopy, X-ray diffraction and thermal gravimetric analysis. Furthermore, the electrochemical properties of NiBC-GS, as electrode materials for supercapacitors, were studied by cyclic voltammetry and galvanostatic charge/discharge in 2 mol L-1  KOH solution. It was determined that for NiBC-GS annealed at 250 ℃, a high specific capacitance of 2394 F g-1 was achieved at a current density of 1 A g-1, with 78% of the value (i.e., 1864F g-1) retained after 5000 times of repeated galvanostatic charge/discharge cycling. The high specific capacitance and available charge/discharge stability indicate the synthesized NiBC-GS250 composite is a good candidate as a novel electrode material for supercapacitors.
KeywordNickel Based Compound Graphene Electrochemical Performance Supercapacitors
Subject Area材料科学与物理化学
DOI10.1016/j.cclet.2015.01.025
Funding Organizationthe National Natural Science Foundation of China (No. 51075348)
Indexed BySCI
If1.947
Language英语
Funding Project聚合物摩擦学组
compositor第一作者单位
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Cited Times:15[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/18483
Collection固体润滑国家重点实验室(LSL)
Corresponding AuthorKong, Xiang-Zheng; Yang SR(杨生荣)
Affiliation1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
2.Univ Jinan, Coll Chem & Chem Engn, Jinan 250022, Peoples R China
3.Chinese Acad Sci, Grad Univ, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Li-Bin,Yang SR,Wang JQ,et al. A facile preparation and electrochemical properties of nickel based compound-graphene sheet composites for supercapacitors[J]. Chinese Chemical Letters,2015,26(5):522-528.
APA Zhang, Li-Bin,Yang SR,Wang JQ,Xu Y,Kong, Xiang-Zheng,&杨生荣.(2015).A facile preparation and electrochemical properties of nickel based compound-graphene sheet composites for supercapacitors.Chinese Chemical Letters,26(5),522-528.
MLA Zhang, Li-Bin,et al."A facile preparation and electrochemical properties of nickel based compound-graphene sheet composites for supercapacitors".Chinese Chemical Letters 26.5(2015):522-528.
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