Room temperature N-alkylation of amines with alcohols under UV irradiation catalyzed by Cu-Mo/TiO2 | |
Department | 绿色化学研究发展中心 |
Zhang LN(张丽娜)1,2; Zhang Y(张妍)1; Deng YQ(邓友全)1; Shi F(石峰)1; Shi F(石峰) | |
The second department | osso国家重点实验室 |
2015 | |
Source Publication | Catalysis Science and Technology |
ISSN | 2044-4753 |
Volume | 5Issue:6Pages:3226-3234 |
Abstract | It is highly desirable to develop efficient heterogeneous photocatalysts for organic reactions. Here, we show the preparation and catalytic performance of a novel TiO2 (P25) supported Cu and Mo photocatalyst (Cu–Mo/TiO2) for N-alkylation of amines with alcohols under UV irradiation at room temperature. A variety of aromatic and aliphatic amines were selectively converted into the corresponding secondary amines or tertiary amines in moderate to excellent yields without the addition of any co-catalysts such as bases and organic ligands. Noteworthy, this catalytic system is feasible in the alkylation of anilines containing halogen substituents with alcohols and the yields of the desired products are up to 95%. |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1039/c5cy00316d |
Funding Organization | the National Natural Science Foundation of China (21203219);the Chinese Academy of Sciences |
Indexed By | SCI |
If | 5.426 |
Language | 英语 |
Funding Project | 纳米催化课题组;绿色催化课题组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/18465 |
Collection | 绿色化学研究发展中心 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Shi F(石峰) |
Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Green Chem & Catalysis, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
Recommended Citation GB/T 7714 | Zhang LN,Zhang Y,Deng YQ,et al. Room temperature N-alkylation of amines with alcohols under UV irradiation catalyzed by Cu-Mo/TiO2[J]. Catalysis Science and Technology,2015,5(6):3226-3234. |
APA | Zhang LN,Zhang Y,Deng YQ,Shi F,&石峰.(2015).Room temperature N-alkylation of amines with alcohols under UV irradiation catalyzed by Cu-Mo/TiO2.Catalysis Science and Technology,5(6),3226-3234. |
MLA | Zhang LN,et al."Room temperature N-alkylation of amines with alcohols under UV irradiation catalyzed by Cu-Mo/TiO2".Catalysis Science and Technology 5.6(2015):3226-3234. |
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c5cy00316d.pdf(2774KB) | 期刊论文 | 出版稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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