| Preparation of nitrogen-functionalized mesoporous carbon and its application for removal of copper ions | |
| Department | OSSO国家重点实验室 |
Li ZY(李治云)1,2 ; Ren SL(任嗣利)1; Ren SL(任嗣利)
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| The second department | 固体润滑国家重点实验室 |
| 2015 | |
| Source Publication | Journal of Materials Science
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| ISSN | 0022-2461 |
| Volume | 50Issue:13Pages:4600-4609 |
| Abstract | Nitrogen-functionalized mesoporous carbon (NMC) materials with high nitrogen content were synthesized through a hard template method using ionic liquid of 1-cyanomethyl-3-methylimidazolium bromide as the precursor and LUDOX HS-40 colloidal silica as the template. The obtained NMCs were characterized by X-ray diffraction, transmission electron microscopy, N2 adsorption and desorption analysis, X-ray photoelectron spectroscopy, and elemental analysis. It was shown that the carbonization temperature played a critical role in determining the physiochemical properties and the nitrogen content of the carbon materials. The obtained nitrogen-functionalized mesoporous carbon carbonized at 800 °C possessed disordered mesoporous structure with very high specific surface area of 1028 m2 g−1, large pore volume of 0.94 cm3 g−1, and high nitrogen content of 21.0 wt%. The adsorption performance of the prepared NMCs was investigated by removing Cu2+ from aqueous solutions and the adsorption capacity could attain 117.1 mg g−1 at an optimal condition. The kinetic and isothermal analysis revealed that the removal of Cu2+ by the NMCs belongs to chemical monolayer adsorption, suggesting the strong interaction between Cu2+ and the adsorbent. The XPS spectra of N1s before and after adsorption of Cu2+ suggested that the pyridinic-type nitrogen was the dominant groups of the adsorbent in the adsorption process. Furthermore, the material was separated from solution by filtration and displayed a superior reusability in the recycling test. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1007/s10853-015-9009-x |
| Funding Organization | the National Natural Science Foundation of China (Grant 51374195);the "100 Talents Program" held by the Chinese Academy of Sciences (CAS) |
| Indexed By | SCI |
| If | 2.302 |
| Language | 英语 |
| Funding Project | 羰基金属功能材料课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/18350 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） 固体润滑国家重点实验室（LSL） |
| Corresponding Author | Ren SL(任嗣利) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China |
| Recommended Citation GB/T 7714 | Li ZY,Ren SL,Ren SL. Preparation of nitrogen-functionalized mesoporous carbon and its application for removal of copper ions[J]. Journal of Materials Science,2015,50(13):4600-4609. |
| APA | Li ZY,Ren SL,&任嗣利.(2015).Preparation of nitrogen-functionalized mesoporous carbon and its application for removal of copper ions.Journal of Materials Science,50(13),4600-4609. |
| MLA | Li ZY,et al."Preparation of nitrogen-functionalized mesoporous carbon and its application for removal of copper ions".Journal of Materials Science 50.13(2015):4600-4609. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 20154600-4609.pdf（2069KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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