| 4-CH3CONH-TEMPO/Peracetic Acid System for a Shortened Electron-Transfer-Cycle-Controlled Oxidation of Secondary Alcohols | |
| Department | OSSO国家重点实验室 |
Zhang SF(张淑芳); Miao CX(苗成霞) ; Xia CG(夏春谷); Sun W(孙伟); Miao CX(苗成霞); Sun W(孙伟)
| |
| 2015 | |
| Source Publication | ChemCatChem
 |
| ISSN | 1867-3880 |
| Volume | 7Issue:12Pages:1865-1870 |
| Abstract | We have developed a 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) derivative catalyzed oxidation of secondary alcohols with peracetic acid as the oxidant, which was generated from H2O2 and acetic acid catalyzed by strongly acidic resins. The oxidation of alcohols proceeded well through a shortened electron-transfer cycle under metal-free conditions, avoiding the use of any other electron-transfer mediators such as halides. In addition, we demonstrated that the present system exhibited excellent efficiency under mild conditions for the oxidation of aromatic, aliphatic, and allylic secondary alcohols. |
| Keyword | Acidity Alcohols Electron Transfer Oxidation |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1002/cctc.201500214 |
| Funding Organization | the National Natural Science Foundation of China (No. 21103207;21133011);the western light program of the Chinese Academy of Sciences (2012) |
| Indexed By | SCI |
| If | 4.724 |
| Language | 英语 |
| Funding Project | 生物与仿生催化课题组;均相催化课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/18335 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Miao CX(苗成霞); Sun W(孙伟) |
| Affiliation | Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Zhang SF,Miao CX,Xia CG,et al. 4-CH3CONH-TEMPO/Peracetic Acid System for a Shortened Electron-Transfer-Cycle-Controlled Oxidation of Secondary Alcohols[J]. ChemCatChem,2015,7(12):1865-1870. |
| APA | Zhang SF,Miao CX,Xia CG,Sun W,苗成霞,&孙伟.(2015).4-CH3CONH-TEMPO/Peracetic Acid System for a Shortened Electron-Transfer-Cycle-Controlled Oxidation of Secondary Alcohols.ChemCatChem,7(12),1865-1870. |
| MLA | Zhang SF,et al."4-CH3CONH-TEMPO/Peracetic Acid System for a Shortened Electron-Transfer-Cycle-Controlled Oxidation of Secondary Alcohols".ChemCatChem 7.12(2015):1865-1870. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| LZ01028414.pdf（452KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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