(EtO)(3)SiH-Promoted Palladium-Catalyzed Isomerization of Olefins: Convenient Synthesis of Internal Alkenes from Terminal Alkenes

doi:10.1055/s-0033-1340290

	(EtO)(3)SiH-Promoted Palladium-Catalyzed Isomerization of Olefins: Convenient Synthesis of Internal Alkenes from Terminal Alkenes
Department	OSSO国家重点实验室
	Bai XF(柏惺峰)1,2,3; Song, Tao 1; Deng WH(邓文慧)1; Wei, Yun-Long 1; Li L(李莉)1; Xia CG(夏春谷)2,3 ; Xu LW(徐利文)1,2,3; Li L(李莉); Xu LW(徐利文)
	2014
Source Publication	SYNLETT
ISSN	0936-5214
Volume	25 Issue:3 Pages:417-422
Abstract	The catalytic activity of an in situ forming palladium catalyst system generated from PdCl₂(PPh₃)₂ and hydrosilane [(EtO)₃SiH] was revealed in the one-carbon migration and isomerization of 4,4-biaryl-substituted 1-butenes, in which the (EtO)₃SiH plays a key role in the palladium-catalyzed one-carbon migration and subsequent isomerization of terminal alkenes. This catalytic protocol is applied in the synthesis of a key building block of cassumunin C in high yield and promising selectivity.
Keyword	Olefin Palladium Isomerization Cassumunin Organosilicon
Subject Area	物理化学与绿色催化
DOI	10.1055/s-0033-1340290
Funding Organization	the National Natural Science Founder of China (NSFC) (Grant No. 21173064);the Zhejiang Provincial Natural Science Foundation of China (ZPNSFC, Q12B020037);the Program for Excellent Young Teachers in Hangzhou Normal University (HNUEYT, JTAS 2011-01-014)
Indexed By	SCI
If	2.419
Language	英语
Funding Project	均相催化课题组
compositor	第二作者单位
Citation statistics	Cited Times:18[WOS] [WOS Record] [Related Records in WOS]
Document Type	期刊论文
Identifier	http://ir.licp.cn/handle/362003/18308
Collection	羰基合成与选择氧化国家重点实验室（OSSO）
Corresponding Author	Li L(李莉); Xu LW(徐利文)
Affiliation	1.Hangzhou Normal Univ, Coll Mat Chem & Chem Engn, Minist Educ, Key Lab Organosilicon Chem & Mat Technol, Hangzhou 310012, Zhejiang, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 3.Chinese Acad Sci, Univ Chinese Acad Sci, Lanzhou 730000, Peoples R China
Recommended Citation GB/T 7714	Bai XF,Song, Tao,Deng WH,et al. (EtO)(3)SiH-Promoted Palladium-Catalyzed Isomerization of Olefins: Convenient Synthesis of Internal Alkenes from Terminal Alkenes[J]. SYNLETT,2014,25(3):417-422.
APA	Bai XF.,Song, Tao.,Deng WH.,Wei, Yun-Long.,Li L.,...&徐利文.(2014).(EtO)(3)SiH-Promoted Palladium-Catalyzed Isomerization of Olefins: Convenient Synthesis of Internal Alkenes from Terminal Alkenes.SYNLETT,25(3),417-422.
MLA	Bai XF,et al."(EtO)(3)SiH-Promoted Palladium-Catalyzed Isomerization of Olefins: Convenient Synthesis of Internal Alkenes from Terminal Alkenes".SYNLETT 25.3(2014):417-422.

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