| Efficient Palladium-Catalyzed CO Hydrogenolysis of Benzylic Alcohols and Aromatic Ketones with Polymethylhydrosiloxane | |
| Department | OSSO国家重点实验室 |
| Wang H(王虎)1; Li L(李莉)1; Bai XF(柏惺峰)1; Shang, Jun-Yan1; Yang KF(杨科芳)1; Xu LW(徐利文)1,2; Yang KF(杨科芳); Xu LW(徐利文) | |
| 2013 | |
| Source Publication | Advanced Synthesis and Catalysis
 |
| ISSN | 1615-4150 |
| Volume | 355Issue:2-3Pages:341-347 |
| Abstract | A simple method has been developed for the reductive deoxygenation of aromatic ketones and benzylic alcohols in the presence of polymethylhydrosiloxane (PMHS). The reductive deoxygenation of aromatic ketones and benzylic alcohols, including secondary alcohols, to the corresponding methylene hydrocarbons has been achieved in good to excellent yields using palladium chloride (PdCl2) as catalyst and PMHS as hydride source. Such deoxygenations were successfully with aryl alkyl ketones and diaryl ketones, as exemplified by the reductive deoxygenation of acetophenone and benzopheneone, respectively. The corresponding benzylic alcohols and secondary alcohol analogues could also be converted into their respective methylene hydrocarbons by the PdCl2/PMHS system. |
| Keyword | Deoxygenation Hydrogenolysis Palladium Reduction Polymethylhydrosiloxane (Pmhs) Silanes |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1002/adsc.201200832 |
| Funding Organization | the National Natural Science Foundation of China (No. 21173064;51203037);Zhejiang Province Natural Science Foundation of China (Q12B020037);the Program for Excellent Young Teachers in Hangzhou Normal University (HNUEYT, JTAS 2011-01-014) |
| Indexed By | SCI |
| If | 5.542 |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/18260 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Yang KF(杨科芳); Xu LW(徐利文) |
| Affiliation | 1.Hangzhou Normal Univ, Minist Educ, Key Lab Organosilicon Chem & Mat Technol, Hangzhou, Zhejiang, Peoples R China 2.Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Wang H,Li L,Bai XF,et al. Efficient Palladium-Catalyzed CO Hydrogenolysis of Benzylic Alcohols and Aromatic Ketones with Polymethylhydrosiloxane[J]. Advanced Synthesis and Catalysis,2013,355(2-3):341-347. |
| APA | Wang H.,Li L.,Bai XF.,Shang, Jun-Yan.,Yang KF.,...&徐利文.(2013).Efficient Palladium-Catalyzed CO Hydrogenolysis of Benzylic Alcohols and Aromatic Ketones with Polymethylhydrosiloxane.Advanced Synthesis and Catalysis,355(2-3),341-347. |
| MLA | Wang H,et al."Efficient Palladium-Catalyzed CO Hydrogenolysis of Benzylic Alcohols and Aromatic Ketones with Polymethylhydrosiloxane".Advanced Synthesis and Catalysis 355.2-3(2013):341-347. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| LZ01027749 .pdf（263KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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