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The electrodeposition and characterisation of low-friction and wear-resistant Co-Ni-P coatings
Department固体润滑国家重点实验室
Ma, C.1; Wang, S. C.1; Wang LP(王立平)2; Walsh, F. C.1,3; Wood, R. J. K.1
2013
Source PublicationSurface and Coatings Technology
ISSN0257-8972
Volume235Pages:495-505
AbstractA new Co-Ni-P coating having superior properties to hard chrome coatings for anti-wear applications has been developed by combining the precipitation hardening of Ni-P alloys with the lubricity of cobalt-rich Co-Ni coatings. The evolution of composition and microstructure, hardness, thermal stability and tribological properties have been investigated. The local pH value near the cathode played an important role in the change of the microstructure from nanoctystalline to amorphous along the growth direction as the phosphorous content increased from 7 at.% to 26 at.%. The highest microhardness (980 HV) and the lowest wear rate (one order of magnitude lower than that of hard chrome coatings under the same dry sliding conditions) were achieved by annealing the coatings at 400 ℃ facilitating precipitation hardening. Furthermore, the coefficients of friction of both the as-deposited Co-Ni-P coating and the heat-treated samples were approximately 03, only half of that of hard chrome coatings. The wear rates of Co-Ni-P coatings annealed up to 400 ℃ are 4-7 times lower compared to that of hard chrome. The roll-like debris found on the worn surfaces of the coating annealed at 500 ℃ were oriented perpendicularly to the sliding direction. Such part might be related to the slightly reduced coefficient of friction in the stable stage.
KeywordCo-ni-p Friction Microstructure Heat Treatment Wear
Subject Area材料科学与物理化学
DOI10.1016/j.surfcoat.2013.08.009
Funding OrganizationICUK
Indexed BySCI
If2.199
Language英语
Funding Project低维材料摩擦学组
compositor第二作者单位
Citation statistics
Cited Times:40[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/18242
Collection固体润滑国家重点实验室(LSL)
Corresponding AuthorWang, S. C.
Affiliation1.Univ Southampton, nCATS, Southampton SO17 1BJ, Hants, England
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China
3.Univ Southampton, Southampton SO17 1BJ, Hants, England
Recommended Citation
GB/T 7714
Ma, C.,Wang, S. C.,Wang LP,et al. The electrodeposition and characterisation of low-friction and wear-resistant Co-Ni-P coatings[J]. Surface and Coatings Technology,2013,235:495-505.
APA Ma, C.,Wang, S. C.,Wang LP,Walsh, F. C.,&Wood, R. J. K..(2013).The electrodeposition and characterisation of low-friction and wear-resistant Co-Ni-P coatings.Surface and Coatings Technology,235,495-505.
MLA Ma, C.,et al."The electrodeposition and characterisation of low-friction and wear-resistant Co-Ni-P coatings".Surface and Coatings Technology 235(2013):495-505.
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