Syntheses, structures and chemical sensing properties of three complexes with mixed ligands of carboxylate and bipyridine | |
Department | 固体润滑国家重点实验室 |
Jiao, Chengli1,2; Li, Fen1; Zhang, Jian1; Li ZP(李章朋)3; Wang, Shuang1,2; Wang, Zhonggang4; Yu, Hao4; Li, Zhibao1,2; Liu, Shuang1,2; Wang, Ziqiang1,2; Jiang, Xia1,2; Sun, Lixian1,5; Xu, Fen5,6 | |
2013 | |
Source Publication | Dalton Transactions |
ISSN | 1477-9226 |
Volume | 42Issue:5Pages:1346-1351 |
Abstract | Three mixed-ligand coordination polymers, [Cu(oda)(2,2'-bipy)]2 (1), Ni2(oda)2(4,4'-bipy)·DMF (2), and [{Ni(oda)(H2O)2}2(µ-4,4'-bipy)]·2H2O (3) were synthesized and characterized. Complex 1 features a 1D chain via intermolecular pi-pi interactions. Complex 2 is a novel 3D microporous coordination polymer with 1D polarized channels. Complex 3 forms a 3D network via extensive hydrogen bonding interactions. Thermogravimetric analyses have been studied. The chemical sensing properties have been investigated in situ by quartz crystal microbalance (QCM). Complex 1 has a good sensitivity to toluene, complexes 2 and 3 have exceptionally high selectivity and sensitivity to water over organic solvents. |
Subject Area | 材料科学与物理化学 |
DOI | 10.1039/c2dt31867a |
Funding Organization | the “973 project” (2010CB631303);NSFC (20833009;51071146;21173111;20903095;51071081;51101145;U0734005;51102230);Liaoning BaiQianWan Talents Program (No. 2010921050);Liaoning Education Committee (L2010223);Solar Energy Action Plan of CAS, IUPAC (Project No. 2008-006-3-100);the Joint Project of Guangdong Province and CAS (2010A090100034);the State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology (Grant No. KFJJ10-1Z) |
Indexed By | SCI |
If | 4.097 |
Language | 英语 |
compositor | 第三作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/18215 |
Collection | 固体润滑国家重点实验室(LSL) |
Affiliation | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China 4.Dalian Univ Technol, Dept Polymer Sci & Engn, State Key Lab Fine Chem, Sch Chem Engn, Dalian 116012, Peoples R China 5.Guilin Univ Elect Technol, Fac Mat Sci & Engn, Guilin 541004, Peoples R China 6.Liaoning Normal Univ, Fac Chem & Chem Engn, Dalian 116029, Peoples R China |
Recommended Citation GB/T 7714 | Jiao, Chengli,Li, Fen,Zhang, Jian,et al. Syntheses, structures and chemical sensing properties of three complexes with mixed ligands of carboxylate and bipyridine[J]. Dalton Transactions,2013,42(5):1346-1351. |
APA | Jiao, Chengli.,Li, Fen.,Zhang, Jian.,Li ZP.,Wang, Shuang.,...&Xu, Fen.(2013).Syntheses, structures and chemical sensing properties of three complexes with mixed ligands of carboxylate and bipyridine.Dalton Transactions,42(5),1346-1351. |
MLA | Jiao, Chengli,et al."Syntheses, structures and chemical sensing properties of three complexes with mixed ligands of carboxylate and bipyridine".Dalton Transactions 42.5(2013):1346-1351. |
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LZ01027680.pdf(1423KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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