LICP OpenIR  > 固体润滑国家重点实验室(LSL)
pH-Responsive Controlled-Release Fertilizer with Water Retention via Atom Transfer Radical Polymerization of Acrylic Acid on Mussel-Inspired Initiator
Department固体润滑国家重点实验室
Ma, Zhi-yuan1; Jia, Xin1; Zhang, Guo-xiang1; Hu, Jia-mei1; Zhang, Xiu-lan1; Liu, Zhi-yong1; Wang, He-yun1; Zhou F(周峰)2
2013
Source PublicationJournal of Agricultural and Food Chemistry
ISSN0021-8561
Volume61Issue:23Pages:5474-5482
AbstractThis work reports a polydopamine-graft-poly(acrylic acid) (Pdop-g-PAA)-coated controlled-release multi-element compound fertilizer with water-retention function by a combination of mussel-inspired chemistry and surface-initiated atom transfer radical polymerization (SI-ATRP) techniques for the first time The morphology and composition of the products were characterized by transmission electron microscopy (TEM), Fourier transform infrared (FTIR) spectroscopy, thermogravimetric analysis (TGA), gel permeation chromatography (GPC), and inductively coupled plasma (ICP) emission spectrometry. The results revealed that the stimuli responsive layer formed by a Pdop inner layer and a PAA outer corona exhibit outstanding selective permeability to charged nutrients and the release rate of encapsulated elements can be tailored by the pH values. At low pH, the Pdop-g-PAA layer can reduce nutrient loss, and at high pH, the coating restrains transportation of negative nutrients but favors the release of cations. Moreover, PAA brushes provide good water retention property. This Pdop-graft-polymer brushes coating will be effective and promising in the research and development of multi functional controlled release fertilizer.
KeywordControlled Release Fertilizer Polydopamine Ph-responsive Poly(Acrylic Acid) Atom Transfer Radical Polymerization
Subject Area材料科学与物理化学
DOI10.1021/jf401102a
Funding Organizationthe National Natural Science Foundation of China (21264013)
Indexed BySCI
If3.107
Language英语
Funding Project材料表面与界面行为研究组
compositor第二作者单位
Citation statistics
Cited Times:56[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/18200
Collection固体润滑国家重点实验室(LSL)
Affiliation1.Shihezi Univ, Key Lab Green Proc Chem Engn Xinjiang Bingtuan, Key Lab Chem Mat Xinjiang Uygur Autonomous Reg, Sch Chem & Chem Engn, Shihezi 832003, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
Recommended Citation
GB/T 7714
Ma, Zhi-yuan,Jia, Xin,Zhang, Guo-xiang,et al. pH-Responsive Controlled-Release Fertilizer with Water Retention via Atom Transfer Radical Polymerization of Acrylic Acid on Mussel-Inspired Initiator[J]. Journal of Agricultural and Food Chemistry,2013,61(23):5474-5482.
APA Ma, Zhi-yuan.,Jia, Xin.,Zhang, Guo-xiang.,Hu, Jia-mei.,Zhang, Xiu-lan.,...&Zhou F.(2013).pH-Responsive Controlled-Release Fertilizer with Water Retention via Atom Transfer Radical Polymerization of Acrylic Acid on Mussel-Inspired Initiator.Journal of Agricultural and Food Chemistry,61(23),5474-5482.
MLA Ma, Zhi-yuan,et al."pH-Responsive Controlled-Release Fertilizer with Water Retention via Atom Transfer Radical Polymerization of Acrylic Acid on Mussel-Inspired Initiator".Journal of Agricultural and Food Chemistry 61.23(2013):5474-5482.
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