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Removal of congo red from aqueous solution by adsorption on organified rectorite
Department环境材料与生态化学研究发展中心
Liu Y(刘毅); Wang WB(王文波); Wang AQ(王爱勤); 王爱勤 aqwang@licp.cas.cn
2010
Source PublicationCLEAN - Soil, Air, Water
ISSN1863-0650
Volume38Issue:7Pages:670-677
AbstractBatch sorption technique was carried out for the removal of anionic dye Congo red (CR) from aqueous solution using raw rectorite (R-REC) and organified rectorite (CTAþ-REC) modified by cetyltrimethylammonium bromide (CTAB) as adsorbents. The effects of organification degree of CTAþ-REC as well as the process parameters including the pH of dye solution, sorption time, and initial dye concentration on adsorption capacity for CR were investigated and the sorption kinetics was also evaluated. The results showed that the sorption behaviors of R-REC and CTAþ-REC for CR followed pseudo-second-order kinetic model and the sorption equilibrium data perfectly obeyed the Langmuir isotherm. The thermodynamic parameters including entropy of sorption (DS0), enthalpy of sorption (DH0), and Gibbs free energy of sorption (DG0) were obtained and analyzed. Fourier transform infrared study revealed that a chemisorption process occurred between CR and CTAþ-REC. REC modified by cationic surfactants showed the higher adsorption capacities for CR compared to R-REC and in theory would be used as an efficient and promising adsorbent for the removal of anionic dyes in wastewater treatment.
KeywordCongo Red Dyes Kinetics Rectorite Sorption Isotherm
Subject Area功能高分子
Funding Organization江苏省科技厅项目(BE2008087)
Indexed BySCI
Language英语
Funding Project功能复合材料组
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/135
Collection环境材料与生态化学研究发展中心
Corresponding Author王爱勤 aqwang@licp.cas.cn
Recommended Citation
GB/T 7714
Liu Y,Wang WB,Wang AQ,et al. Removal of congo red from aqueous solution by adsorption on organified rectorite[J]. CLEAN - Soil, Air, Water,2010,38(7):670-677.
APA 刘毅,王文波,王爱勤,&王爱勤 aqwang@licp.cas.cn.(2010).Removal of congo red from aqueous solution by adsorption on organified rectorite.CLEAN - Soil, Air, Water,38(7),670-677.
MLA 刘毅,et al."Removal of congo red from aqueous solution by adsorption on organified rectorite".CLEAN - Soil, Air, Water 38.7(2010):670-677.
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