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Construction and study on corrosion protective property of polydopamine-based 3-layer organic coatings on aluminum substrate
Department固体润滑国家重点实验室
Ou JF(欧军飞); Wang JQ(王金清); Zhou JF(周金芳); Liu S(刘胜); Yu YL(于元烈); Pang XJ(逄显娟); Yang SR(杨生荣)
2010
Source PublicationProgress in Organic Coatings
ISSN0300-9440
Volume68Pages:244-247
AbstractMetal aluminum (Al) is being widely used in industry and can be easily corroded in severe conditions. Recently, dopamine has been demonstrated to be an effective adhesive molecular that can be attached to virtually all material surfaces to form stable polydopamine coating (PDAc), exhibiting promiprospects in many fields. In this work, to improve the anti-corrosion performance of Al sheet, a npolydopamine-based 3-layer organic coating has been constructed by a multi-step self-assembly tnique for the first time. In brief, a self-assembled monolayer of (3-mercaptopropyl)trimethoxysi(coded as MPTS-SAM) was firstly prepared for enhancing the adhesion between the PDAc and thsubstrate. Subsequently, a PDAc was assembled onto the Al substrate by a simple immersion intodopamine hydrochloride solution at a pH of 8.5. At last, a layer of tetradecanoyl chloride was graonto the PDAc surface through amidation, which could apparently slow down the water diffusion tointerface of PDAc and Al for its prominent hydrophobicity. Corrosion resistance of the synthesized cing in NaCl solutionwas evaluated by potentiodynamic polarization test and electrochemical impedspectroscopy (EIS) measurement, respectively. As results show, PDAc on bare Al can protect the strate from corrosion to a certain extent. Significantly, after being mediated by MPTS-SAM underland covered by tetradecanoyl chloride outer layer, the anti-corrosion capability of the coating has been improved markedly.
KeywordPolydopamine 3-layer Coating Aluminum Eletrochemistry Corrosion
Subject Area材料科学与物理化学
Funding Organizationthe National Natural Science Foundation of China (Grant No. 20823008, 50801065);“Top Hundred Talents Program” of Chinese Academy of Sciences
Indexed BySCI
Language英语
Funding Project聚合物摩擦学组
Citation statistics
Cited Times:49[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/1057
Collection固体润滑国家重点实验室(LSL)
Corresponding AuthorWang JQ(王金清); Yang SR(杨生荣)
Recommended Citation
GB/T 7714
Ou JF,Wang JQ,Zhou JF,et al. Construction and study on corrosion protective property of polydopamine-based 3-layer organic coatings on aluminum substrate[J]. Progress in Organic Coatings,2010,68:244-247.
APA 欧军飞.,王金清.,周金芳.,刘胜.,于元烈.,...&杨生荣.(2010).Construction and study on corrosion protective property of polydopamine-based 3-layer organic coatings on aluminum substrate.Progress in Organic Coatings,68,244-247.
MLA 欧军飞,et al."Construction and study on corrosion protective property of polydopamine-based 3-layer organic coatings on aluminum substrate".Progress in Organic Coatings 68(2010):244-247.
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