| Solvent annealing assisted self-assembly of hydrogen-bonded interpolymer complexes of AB block copolymer/C homopolymer in thin film | |
| Department | 固体润滑国家重点实验室 ; 先进润滑与防护材料研究发展中心 |
Wang C(王超) ; Wang TM(王廷梅); Wang QH(王齐华)
| |
| 2010 | |
| Source Publication | Polymer
 |
| ISSN | 0032-3861 |
| Volume | 51Pages:4836-4842 |
| Abstract | A simple process of solvent annealing has been shown to produce ordered self-assembly structures ofpoly(styrene)-block-poly(4-vinylpyridine) (PS-b-P4VP)/poly(4,40-oxydiphenylenepyromellitamic acid)(POAA) block copolymer/homopolymer blends in thin film, where POAA chains selectively interact withP4VP blocks by strong interpolymer hydrogen-bonding. By simply exposing the thin film to benzene/NMP (0.97/0.03, in volume) vapor mixture, ordered microphase-separated structures with PS sphericalmicrodomains distributed within P4VP/POAA complexes matrix were obtained. The formation of themicrophase-separated structures could be attributed to the substantial mobility of PS blocks and P4VP/POAA complexes and enhanced repulsion between them under the benzene/NMP mixture vapor. Whenthe volume ratio of benzene to NMP increased to 0.98/0.02, the increasing benzene in the mixture vaporinduced the adhesive collision of spherical microphase-separated structures to form long “pearl neck-laces”. With increasing volume ratio of benzene to NMP to 0.99/0.01, an ordered “pearl necklace” arrayoriented parallel to the film surface formed. The self-assembly structures were studied by FTIR spec-troscopy, atomic force microscopy (AFM), and transmission electron microscopy (TEM). Finally, possiblemechanism of self-assembly and formation of microphase morphology was proposed. |
| Keyword | Block Copolymer/homopolymer Self-assembly Solvent Annealing |
| Subject Area | 材料科学与物理化学 |
| Funding Organization | the important direction project for the knowledge innovative engineering of Chinese Academy of Sciences (Grant No.KGCX3- SYW-205);the National 973 project of China (2007CB607601) |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 聚合物自润滑复合材料组 |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/1054 |
| Collection | 固体润滑国家重点实验室（LSL） 中国科学院材料磨损与防护重点实验室/先进润滑与防护材料研究发展中心 |
| Corresponding Author | Wang TM(王廷梅); Wang QH(王齐华) |
| Recommended Citation GB/T 7714 | Wang C,Wang TM,Wang QH. Solvent annealing assisted self-assembly of hydrogen-bonded interpolymer complexes of AB block copolymer/C homopolymer in thin film[J]. Polymer,2010,51:4836-4842. |
| APA | 王超,王廷梅,&王齐华.(2010).Solvent annealing assisted self-assembly of hydrogen-bonded interpolymer complexes of AB block copolymer/C homopolymer in thin film.Polymer,51,4836-4842. |
| MLA | 王超,et al."Solvent annealing assisted self-assembly of hydrogen-bonded interpolymer complexes of AB block copolymer/C homopolymer in thin film".Polymer 51(2010):4836-4842. |
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| 20104836-4842.pdf（1820KB） | 开放获取 | License | View Application Full Text | |||
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